By Motasem Haddadin Nicholas P. Cheremisinoff
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Extra info for Beyond Compliance: The Refinery Manager's Guide to ISO 14001 Implementation
A full-scale (130 MW) gasifier was built in the 1980s to produce syngas and town gas. The technology was known as the GSP process before being acquired by Noell in 1991. The process can be a dry-fed or liquid-fed oxygen-blown slagging gasifier. If solid fuel is to be gasified, it is first pulverized, then pneumatically conveyed to the feeding system and dry fed together with oxygen and steam through a burner located at the top of the gasifier. Depending on the fuel ash content, the gasification chamber can be covered by either a cooling screen or a cooling wall.
The H2S in the tail gas is absorbed and converted to zinc sulfide by the bed. When the bed is loaded, it is regenerated using a diluent air stream. The zinc sulfide is converted back to zinc oxide and the Refining Operations and the Sources of Pollution 39 sulfur goes t o S O 2. The regeneration gas stream containing the S O 2 then is recycled to the Claus unit. The Claus unit is operated to produce a high H2S/SO 2 ratio, since the zinc oxide does not react with SO 2. Z-SORB should be able to guarantee recoveries in the mid 99%; however, Phillips is no longer offering this process for license.
Most of the ammonia (NH3)and some of the carbon dioxide (CO2)and H2S present in the syngas are absorbed in the water as dissolved gases. Wabash River (Indiana) plant is the only E-Gas gasifier in operation. Prior to the repowering of the Wabash River plant to an IGCC, some tests of bituminous coals, including high-sulfur coals, were performed in a 2200 t coal/d plant based in Plaquemine, Louisiana, in the early 1990s. 4 MJ/Kg (moisture and ash free). It is presently operating on Illinois No. 6 coal.