By William J. Koros
content material: Barrier polymers and buildings : evaluate / William J. Koros --
basics of gasoline diffusion in rubbery and glassy polymers / S.A. Stern and S. Trohalaki --
results of structural order on barrier homes / D.H. Weinkauf and D.R. Paul --
shipping of plasticizing penetrants in glassy polymers / Alan R. Berens --
constitution of amorphous polyamides : influence on oxygen permeation homes / Timothy D. Krizan, John C. Coburn, and Philip S. Blatz --
shipping of penetrant molecules via copolymers of vinylidene chloride and vinyl chloride / J. Bicerano, A.F. Burmester, P.T. DeLassus, and R.A. Wessling --
gasoline delivery via bisphenol-containing polymers / John C. Schmidhauser and Kathryn L. Longley --
Water delivery via polymers : requisites and designs in nutrition packaging / Leonard E. Gerlowski --
Barrier homes of ethylene-vinyl alcohol copolymer in retorted plastic nutrients bins / Boh C. Tsai and James A. Wachtel --
Retortable nutrients programs containing water-sensitive oxygen barrier / M.M. Alger, T.J. Stanley, and J. Day --
functionality of high-barrier resins with platelet-type fillers : results of platelet orientation / T.C. Bissot --
Permeability of aggressive oxygen-barrier resins : orientability and influence of orientation / R. Shastri, H.C. Roehrs, C.N. Brown, and S.E. Dollinger --
Polymer blends : morphology and solvent limitations / P.M. Subramanian --
development in barrier homes of polymers through sulfonation and reductive metallization / W.E. Walles --
Fluorinated high-density polyethylene barrier boxes : functionality features / J.P. Hobbs, M. Anand, and B.A. Campion --
Packaging of juices utilizing polymeric barrier bins / J. Miltz, C.H. Mannheim, and B.R. Harte --
lack of taste compounds from aseptically processed nutrition items packaged in aseptic boxes / A.P. Hansen and D.K. Arora --
Diffusion and sorption of linear esters in chosen polymer motion pictures / G. Strandburg, P.T. DeLassus, and B.A. Howell --
Sorption and diffusion of monocyclic fragrant compounds via polyurethane membranes / U. Shanthamurthy Aithal, Tejraj M. Aminabhavi, and Patrick E. Cassidy --
Toluene diffusion in normal rubber / Lawrence S. Waksman, Nathaniel S. Schneider, and Nak-Ho Sung.
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Extra info for Barrier Polymers and Structures
In these investigators membranes different populations However, slower consisted differed between i s not c o n s i s t e n t model, and was fluorophore molecules transition i s lowered of two the fluorophore d i s p e r s e d molecular The d i f f u s i o n the experimental sorption The that by two o r d e r s exchange ture found mobilities. t h e exchange than fluorescence photobleach- dye) i n g l a s s y p o l y ( 1 - t r i m e t h y l s y l i l - l - p r o p y n e ) mem These widely known as " l a s e r (FPR) t o s t u d y t h e i n - p l a n e d i f f u s i o n o f a f l u o r o p h o r e populations coefficients o f magnitude, c f .
Brandt's average 28 BARRIER POLYMERS AND STRUCTURES (a) CHAINS MOLECULE B u n d l e of ParaMti I Polymer Segments NORMAL S T A T E Penetrant Molecule ACTIVATED STATE (C) F i g u r e 1. a) B r a n d t ' s model o f t h e a c t i v a t e d s t a t e f o r d i f f u s i o n . ( R e p r i n t e d f r o m J . Phys. W. Brandt. ) b) The A c t i v a t i o n d i f f u s i o n p r o c e s s a c c o r d i n g t o D i B e n e d e t t o and P a u l . T. R. P a u l , J . Polym. S c i . , A, 2, 1001, 1964, copyright 1964 John W i l e y & Sons, I n c .
J 1 I I 35*C 1 —Ο ο—ο— — 20°C —o . Λ. 8 0-6 Figure 0 3a. I 2 1 4 1 I ι 6 θ 10 MEAN PRESSURE^ (atm) 1 12 14 Comparison o f e x p e r i m e n t a l p e r m e a b i l i t y c o e f f i c i e n t s w i t h v a l u e s p r e d i c t e d by S t e r n , F r i s c h , and c o w o r k e r s ' e x t e n s i o n o f F u j i t a ' s f r e e - v o l u m e model f o r Ar i n polyethylene. ( S . A . S t e r n , S. R. Sampat, and S. S. K u l k a r n i , J . Polym. S c i . : P a r t B: Polym. , 24, 2149, 1986, c o p y r i g h t 1986 John W i l e y & Sons, I n c .